Unlocking high hole mobility in diamond over a wide temperature range via efficient shear strain

作者：J. R. Sun, Shouhang Li, Cheng Shao, Zhen Tong, Meng An, Yuhang Yao, Yue Hu, Xiongfei Zhu, Yifan Liu, Renzong Wang, Xiangjun Liu, Thomas Frauenheim · 发表于：Applied Physics Reviews · 年份：2025 · DOI：10.1063/5.0245795 · 被引用次数：7 · 研究领域：Diamond and Carbon-based Materials Research、High-pressure geophysics and materials、Metal and Thin Film Mechanics

As a wide bandgap semiconductor, diamond holds both excellent electrical and thermal properties, making it highly promising in the electrical industry. However, its hole mobility is relatively low and dramatically decreases with increasing temperature, which severely limits further applications. Herein, we proposed that the hole mobility can be efficiently enhanced via slight compressive shear strain along the [100] direction, while the improvement via shear strain along the [111] direction is marginal. This impressive distinction is attributed to the deformation potential and the elastic compliance matrix. The shear strain breaks the symmetry of the crystalline structure and lifts the band degeneracy near the valence band edge, resulting in a significant suppression of interband electron–phonon scattering. Moreover, the hole mobility becomes less temperature-dependent due to the decrease of electron scatterings from high-frequency acoustic phonons. Remarkably, the in-plane hole mobility of diamond is increased by ∼800% at 800 K with a 2% compressive shear strain along the [100] direction. The efficient shear strain strategy can be further extended to other semiconductors with face-centered cubic geometry.