Dual‐Source Evaporation Processed Novel NaBiS 2 Absorber Material for Eco‐Friendly and Stable Photovoltaics

作者：Zijun Yi, Long Zhang, Wenguang Zhang, Yihuai Huang, Yuchen Xiong, Changkai Huang, Guibin Shen, Abdul Basit, Xuehong Ren, Yubo Luo, Xin Li, Junyou Yang · 发表于：Small · 年份：2025 · DOI：10.1002/smll.202411032 · 被引用次数：10 · 研究领域：Chalcogenide Semiconductor Thin Films、Perovskite Materials and Applications、Quantum Dots Synthesis And Properties

Abstract Exploring and developing novel, low‐cost, and environmentally friendly photovoltaic materials is a vital trend in the evolution of solar cell technology. The distinctive properties of alkali bismuth ternary sulfides have spurred increased research and application in optoelectronic devices. In this study, a novel method is reported for preparing NaBiS 2 film by sequential thermal evaporation of Na 2 S and Bi 2 S 3 layers followed by heating post‐treatment for the first time, as well as the preparation of solar cells with NaBiS 2 as the light‐absorbing layer. Based on X‐ray diffraction and Raman analysis, the prepared NaBiS 2 film is confirmed to be a single‐phase material, without the presence of any secondary phases. Additionally, the photoelectric characteristics of NaBiS 2 are investigated and incorporated this material into solar cell devices. By optimizing the device architecture, the solar cell utilizing NaBiS 2 as the light‐absorbing layer achieved a photoelectric conversion efficiency of 2.91%, which is the highest efficiency reported for NaBiS 2 solar cells up to now. The research has provided a valuable perspective and path for the development of novel photovoltaic materials in the solar cell field.