Modular assembly of amines and diborons with photocatalysis enabled halogen atom transfer of organohalides for C(sp 3 )–C(sp 3 ) bond formation

作者：Rong‐Bin Liang, Tingting Miao, Xiang-Rui Li, Jia-Bo Huang, Shao‐Fei Ni, Sanliang Li, Qing‐Xiao Tong, Jian‐Ji Zhong · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc00190k · 被引用次数：21 · 研究领域：Radical Photochemical Reactions、Organoboron and organosilicon chemistry、Sulfur-Based Synthesis Techniques

B1. The strategy features operational simplicity, mild conditions and good functional group tolerance. A range of organohalides including activated alkyl chlorides, alkyl bromides (1°, 2° and 3° C-Br) as well as aromatic bromides are applicable in the strategy. Experimental and computational studies rationalize the proposed mechanism.