Modulating Built‐In Electric Field Strength in Ru/RuO 2 Interfaces through Ni Doping to Enhance Hydrogen Conversion at Ampere‐level Current

作者：Tao Liu, Lianqin Wang, Bin Chen, Haotian Liu, Sipu Wang, Yingjie Feng, Junfeng Zhang, Yan Yin, Guiver Michael · 发表于：Angewandte Chemie · 年份：2025 · DOI：10.1002/ange.202421869 · 被引用次数：5 · 研究领域：Electrocatalysts for Energy Conversion、Advanced battery technologies research、Electrochemical Analysis and Applications

Abstract Improving the alkaline hydrogen evolution reaction (HER) efficiency is essential for developing advanced anion exchange membrane water electrolyzers (AEMWEs) that operate at industrial ampere‐level currents. Herein, we employ density functional theory (DFT) calculations to identify Ni‐RuO 2 as the leading candidate among various 3d transition metal‐doped M‐RuO 2 (where metal M includes Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn). The incorporation of Ni atoms facilitates the partial reduction of RuO 2 , resulting in the formation of a Ni−Ru/RuO 2 interface having a significant built‐in electric field (BIEF) during electrochemical reactions. The resulted BIEF enhances electron transfer across the interface, which is critical in lowering energy barriers and accelerating the hydrogen evolution reaction (HER) kinetics. As a result, the Ni‐RuO 2 catalyst exhibits an overpotential of 134 mV at 1 A cm −2 and a low Tafel slope of 20.85 mV dec −1 , with just 0.03 mg cm −2 of Ru loading. The highly effective BIEF, therefore, plays a pivotal role in the catalyst‘s remarkable performance, allowing the Ni‐RuO 2 ‐based AEMWE to require only 1.71 V to maintain stable operation at 1 A cm −2 over a 1000‐hour period.