Critical Role of Tetrahedral Coordination in Determining the Polysulfide Conversion Efficiency on Spinel Oxides

作者：Wen Xie, Samuel Jun Hoong Ong, Zihan Shen, Liying Tian, Kai Tang, Shibo Xi, Zhichuan J. Xu · 发表于：Journal of the American Chemical Society · 年份：2024 · DOI：10.1021/jacs.4c14263 · 被引用次数：37 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Polyoxometalates: Synthesis and Applications

Understanding the structure–property relationship and the way in which catalysts facilitate polysulfide conversion is crucial for the rational design of lithium–sulfur (Li–S) battery catalysts. Herein, a series of NiAl 2 O 4, CoAl 2 O 4, and CuAl 2 O 4 spinel oxides with varying Ni 2+, Co 2+, or Cu 2+ tetrahedral and octahedral site occupancy are studied as Li–S battery catalysts. Combined with experimental and theoretical analysis, the tetrahedral site is identified as the most active site for enhancing polysulfide adsorption and charge transfer. This work demonstrates the geometric configuration dependence of spinel oxides for polysulfide conversion and highlights the role of the molecular orbital in determining the activity of cations in different geometries, thereby providing new insights into the rational design of Li–S battery catalysts.