Palladium-catalysed asymmetric cascade transformations of 4-alken-2-ynyl carbonates to construct complex frameworks

作者：Ze-Liang He, Li Li, Zhichao Chen, Wei Du, Ying‐Chun Chen · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d4sc07823c · 被引用次数：6 · 研究领域：Catalytic C–H Functionalization Methods、Catalytic Alkyne Reactions、Asymmetric Synthesis and Catalysis

-aminophenyl-tethered activated alkenes to afford the analogous alkaloid architectures. This palladium-catalysed auto-tandem protocol exhibits excellent chemo-, regio-, stereoselectivity and reaction efficacy, and substantial functionality compatibility is also observed.