C–H silylation and boronation enabled by alkyne insertion/vinyl to aryl 1,5-palladium migration

作者：Zhendong Cheng, Weiwei Xu, Xuliang Tan, Zhengrui Zhou, Liwei Zhou, Yun Liang, Yuan Yang · 发表于：Organic Chemistry Frontiers · 年份：2024 · DOI：10.1039/d4qo02224f · 被引用次数：12 · 研究领域：Catalytic Cross-Coupling Reactions、Catalytic C–H Functionalization Methods、Fluorine in Organic Chemistry

An alkyne insertion/vinyl to aryl 1,5-palladium migration strategy has been disclosed for the α-C–H silylation and boronation of a naphthalene ring, enabling the synthesis of silylated and boronated benzo[ f ]isoquinolines and benzo[ f ]isochromenes.