Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

作者：Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan · 发表于：Small · 年份：2024 · DOI：10.1002/smll.202409997 · 被引用次数：16 · 研究领域：Crystal Structures and Properties、Iron-based superconductors research、High-pressure geophysics and materials

Abstract Infrared nonlinear optical (NLO) crystal materials exert a crucial role in laser technology, which is extensively utilized in the fields of medical laser, long‐distance laser communication, infrared laser guidance, etc . Currently, the commercially available infrared NLO crystals are diamond‐like structural crystals AgGaQ 2 (Q = S, Se) and ZnGeP 2 . However, their applications are significantly limited owing to their inherent drawbacks, such as low laser damage thresholds and narrow band gaps. Therefore, exploring novel infrared NLO materials with excellent performances is urgent. At present, candidate systems for exploring infrared NLO materials mainly are chalcogenides, pnictides, metal halides for popular systems, and chalcohalides, oxyhalides, heavy metal oxides, oxychalcogenides, nitrides for emergent systems. Notably, among them, pnictides generally exhibited a stronger NLO performance than other systems, but a narrower band gap. Accordingly, after the detailed literature survey, to the best knowledge, ≈139 compounds achieve balanced performances ( E g ≥ 3.0 eV, d ij ≥ 0.5 × AgGaS 2 ) in the remaining systems, in which there are 2 metal halides, 9 oxyhalides, 10 heavy metal oxides, 17 nitrides, 19 oxychalcogenides, 22 chalcohalides, and 60 chalcogenides. Thus, the structure‐property survey of these compounds produces the practical design strategy to explore emergent infrared NLO crystal materials with balanced properties.