Distribution of Polycyclic Aromatic Hydrocarbons and Pesticides in Danjiangkou Reservoir and Evaluation of Ecological Risk

作者：Ruiwen Li, Hao Pang, Yemin Guo, Xuan Zhou, Kaiyu Fu, Taotao Zhang, Jian Han, Lihua Yang, Bingsheng Zhou, Si Zhou · 发表于：Toxics · 年份：2024 · DOI：10.3390/toxics12120859 · 被引用次数：5 · 研究领域：Toxic Organic Pollutants Impact、Environmental Toxicology and Ecotoxicology、Pesticide and Herbicide Environmental Studies

The Danjiangkou Reservoir is the largest artificial freshwater lake in Asia. This study investigated the spatiotemporal distribution of pesticides and polycyclic aromatic hydrocarbons (PAHs) in the Danjiangkou Reservoir to assess the ecological and human health risks associated with these pollutants. Twenty-three sampling sites in the Danjiangkou Reservoir each collected 23 surface water samples and 23 sediment samples. These samples were analyzed using gas chromatography-mass spectrometry (GC-MS), combined with risk quotient methods and health risk assessment models. The results indicated that the total concentration of PAHs (ΣPAHs) in the surface water ranged from 64.64 to 868.23 ng/L (average 217.97 ± 184.97 ng/L), and they primarily consisted of low molecular weight PAHs, with the compounds with the highest concentrations being naphthalene (10.43-116.97 ng/L), fluorene (22.74-87.61 ng/L), and phenanthrene (26.54-162.86 ng/L). The total concentration of pesticides in the surface water varied between 2.62 and 72.89 ng/L (average 22.99 ± 18.27 ng/L). In the sediment samples, the ΣPAH concentration ranged from 0.01 to 2.93 ng/g (average 0.69 ± 0.94 ng/g), and these predominantly consisted of high molecular weight PAHs, while pesticide concentrations ranged from non-detectable (nd) to 28.46 ng/g (average 7.99 ± 8.53 ng/g), with higher concentrations of malathion (0.62-9.16 ng/g) and chlorpyrifos (10.01-21.38 ng/g). Through risk assessment, it was found that although the risks ...