Nitrogen-Doped Graphene-Supported Tungsten Oxynitride Nanoparticles as an Efficient Bidirectional Polysulfide Convertor for Advanced Lithium–Sulfur Batteries

作者：Lulu Suo, Lei Feng, Juan Wang, Miaomiao Xing, Shuhua Lv, Hongyu Mou, Xing Gao, Deliang Zhang, Jibin Song · 发表于：Nano Letters · 年份：2024 · DOI：10.1021/acs.nanolett.4c04791 · 被引用次数：10 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Advanced battery technologies research

Catalytic materials are considered pivotal in addressing the sluggish kinetics and shuttle effect in lithium–sulfur batteries (LSBs). However, effectively harnessing the utilization rate of active sites within catalytic materials remains a pivotal challenge. In this study, a novel conductive nitrogen-doped graphene-loaded tungsten oxynitride nanoparticle (WNO/NG) with abundant active sites is prepared through a polymer-assisted templating method for serving as a sulfur host. Electrochemical analysis coupled with in situ XRD confirm the dual-directional electrocatalytic behavior of WNO/NG for accelerating the conversion of lithium polysulfide (LiPSs). Theoretical calculations demonstrate that the intrinsic mechanism underlying the performance enhancement is attributed to the high inherent conductivity of WNO/NG and the efficient interface charge transfer with LiPSs. The assembled 500 mAh pouch cell delivers a 97% capacity retention after 25 cycles. This strategy provides valuable insights for designing catalytic materials with abundant activity sites and sheds light on the mechanisms of catalytic enhancement in Li–S chemistry.