Aeration‐Free Photo‐Fenton‐Like Reaction Mediated by Heterojunction Photocatalyst toward Efficient Degradation of Organic Pollutants

作者：Yan Wang, Lianxin Li, Puyang Zhou, Yu Gan, Weipeng Liu, Yiwen Wang, Yilin Deng, Hongping Li, Meng Xie, Yuanguo Xu · 发表于：Angewandte Chemie International Edition · 年份：2024 · DOI：10.1002/anie.202419680 · 被引用次数：53 · 研究领域：Advanced oxidation water treatment、Advanced Photocatalysis Techniques、Advanced Nanomaterials in Catalysis

Abstract The regulation of peroxymonosulfate (PMS) activation by photo‐assisted heterogeneous catalysis is under in‐depth investigation with potential as a replaceable advanced oxidation process in water purification, yet it remains a significant challenge. Herein, we demonstrate a strategy to construct polyethylene glycol (PEG) well‐coupled dual‐defect V O −M–Co 3 O 4 @CN x S‐scheme heterojunction to degrade organic pollutants without aeration, which dramatically provides abundant active sites, excellent photo‐thermal property, and distinct charge transport pathway for PMS activation. The degradation rate of V O −M−Co 3 O 4 @CN x in anaerobic conditions shows a higher efficient rate (4.58 min −1 g −2 ) than in aerobic conditions (1.67 min −1 g −2 ). Experimental evidence reveals that V O −M−Co 3 O 4 @CN x promotes more rapid redox conversion of photoexcited electrons induced by defects with PMS under anaerobic conditions compared to aerobic conditions. Additionally, in situ experiments and DFT provide mechanistic insights into the regulation pathway of PMS activation via synergistic defect‐induced electron, revealing the competitive effect between O 2 and PMS over V O −M−Co 3 O 4 @CN x during the reaction process. The continuous flow reactor and flow cytometry results demonstrated that the V O −M−Co 3 O 4 @CN x /PMS/Vis system has remarkably enhanced stability and purification capability for removing organic pollutants. This work provides valuable insights into regulating th...