DIPEA-induced Si–H activation of siloxane for hydrosilylation polymerization via metal-free photocatalysis

作者：Hangcen Xie, Rui Xu, Bin Huang, Pingping Lou, Hua‐Feng Fei, Zhijie Zhang · 发表于：Green Chemistry · 年份：2024 · DOI：10.1039/d4gc04501g · 被引用次数：9 · 研究领域：Organoboron and organosilicon chemistry、Advanced Photocatalysis Techniques、Fuel Cells and Related Materials

A visible light-driven metal-free hydrosilylation reaction catalyzed by the photooxidation catalyst 3DPAFIPN and the base DIPEA was reported. Mechanistic studies revealed that the reaction is a free radical reaction and thermodynamically feasible.