Covalent Organic Framework Packed Nanoporous Membrane for Continuous Removal of Bisphenol A from Agricultural Irrigation Wastewater

作者：Haonan Qu, Dongmei An, Guang Li, Weiwei Xu, Cuiguang Ma, Haifan Zhang, Ehsan Bahojb Noruzi, Jing Cheng, Chuan Zhou, Govindasami Periyasami, Haibing Li · 发表于：ACS Applied Materials & Interfaces · 年份：2024 · DOI：10.1021/acsami.4c12738 · 被引用次数：5 · 研究领域：Covalent Organic Framework Applications、Adsorption and biosorption for pollutant removal、Membrane Separation Technologies

BPA, a typical endocrine disruptor, poses a significant threat to the growth of crops and thereby jeopardizes sustainable agriculture products and human health. In this work, a water-stabilized imine covalent organic framework (TpBD-COF) packed nanochannel membrane was constructed. The TpBD-COF membrane achieves high selective removal of BPA attributed to the subdivision of the pores by the filled COF, which further reduces the porous size and effectively eliminates the distance barrier between the selective sites of TpBD-COF membranes and BPA. The selective removal ratio of BPA was 5.79 times higher than that of the bare membrane, while the removal capacity reached 6.78 nM cm –2 min –1 . It can eliminate BPA from irrigation wastewater and ensure crop growth. The application of COF-filled nanoporous membrane provides not only a size-matching strategy for the development of specific continuous removal of BPA but also a theoretical reference for membrane removal of other organic pollutants in agricultural irrigation water environment.