Progress and challenges in structural, in situ and operando characterization of single-atom catalysts by X-ray based synchrotron radiation techniques

作者：Yuhang Liu, Xiaozhi Su, Jie Ding, Jing Zhou, Zhen Liu, Xiangjun Wei, Hong Bin Yang, Bin Liu · 发表于：Chemical Society Reviews · 年份：2024 · DOI：10.1039/d3cs00967j · 被引用次数：122 · 研究领域：Catalytic Processes in Materials Science、Electrocatalysts for Energy Conversion、Catalysis and Oxidation Reactions

observation of SACs under reaction conditions. We emphasize the correlation between spectral fine features and structural characteristics of SACs, along with their analytical limitations. The development of IMST with spatial and temporal resolution is also discussed along with their significance in revealing the structural characteristics and reaction mechanisms of SACs. Additionally, this review explores the study of active center states using spectral fine characteristics combined with theoretical simulations, as well as spectroscopic analysis strategies utilizing machine learning methods to address challenges posed by atomic distribution inhomogeneity in SACs while envisaging potential applications integrating artificial intelligence seamlessly with experiments for real-time monitoring of single-atom catalytic processes.