Electric Field-Induced Enhanced Raman Spectroscopy Sensor and Photocatalysis with Thermoelectric–Plasmonic Metal Nanocomposites

作者：Si Qiu, Yang Wu, Zhen Li, Mingrui Shao, Jibing Tan, Baoqiang Du, Chao Zhang, Zhongbin Pan, Chonghui Li, Xiaofei Zhao · 发表于：The Journal of Physical Chemistry Letters · 年份：2024 · DOI：10.1021/acs.jpclett.4c01870 · 被引用次数：12 · 研究领域：Gold and Silver Nanoparticles Synthesis and Applications、Gas Sensing Nanomaterials and Sensors、Electrochemical Analysis and Applications

Electric field-induced surface-enhanced Raman scattering (E-SERS) substrates have been proven to further enhance the attained Raman intensity. Herein, integrated with plasmonic Ag nanoparticles (Ag NPs), the thermoelectric Bi 2 Te 3 plate as an E-SERS substrate decreased the limit of detection by 2 orders of magnitude and increased the SERS signal by >20 times compared to those without electrical field induction. The thermoelectric potential produced by the Bi 2 Te 3 plate could modulate the electron density and subsequently change the Fermi level of Ag. This increases the resonant electron transition probability using a broad range of molecules. The plasmon-activated catalytic reactions of the interconversion between p -nitrothiophenol and p, p ′-dimercaptoazobenzene could be controlled through the E-SERS template. On the basis of the finite element method, explicit theoretical analysis indicated that the Ag NP–Bi 2 Te 3 –molecule charge transfer could improve our understanding of the SERS and photocatalytic mechanism.