Fe/Zr binary MOF-based separator for highly efficient polysulfide adsorption and conversion in Li-S batteries

作者：Rameez Razaq, Nima Allahgholi, Mir Mehraj Ud Din, Didrik R. Småbråten, Tor Olav Sunde, Önder Tekinalp, Zainab Waris, Xueru Wang, Daniel Rettenwander, Liyuan Deng · 发表于：Journal of Power Sources · 年份：2024 · DOI：10.1016/j.jpowsour.2024.235527 · 被引用次数：12 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Extraction and Separation Processes

Lithium-sulfur (Li-S) batteries are known as a next-generation energy storage technology due to their high theoretical energy density and low cost. However, the shuttling of soluble lithium polysulfides (LPS) between electrodes hinders the practical realization of Li-S batteries, resulting in short cycle life. To address this issue, this work discloses a highly efficient separator with Fe/Zr binary metal-organic framework (MOF) coated on a polypropylene (PP) separator. Fe 3+ metal ions were integrated into the UiO-66(Zr)-NH 2 framework through a simple one-step hydrothermal method. The adsorption test confirmed the superior LPS adsorption capability of the UiO-66(Fe/Zr)-NH 2 than monometallic UiO-66(Zr)-NH 2 , which provides not only uniform-sized nanochannels for effective LPS sorption and even Li + ions transport but also Fe active sites for electrocatalytic conversion of the LPS. UiO-66(Fe/Zr)-NH 2 -based Li symmetrical cells demonstrated a uniform stripping and plating of Li at exceptionally higher current densities (1–10 mA cm −2 ). CR2023 coin cell Li-S battery using a S-CNT/GO composite cathode and UiO-66(Fe/Zr)-NH 2 /PP separator delivered an initial discharge capacity of 900 mAh/g at 0.3C and a long cycle life (820 cycles) with minimal capacity decay of merely 0.067 % per cycle. The significantly improved performance demonstrates the potential of binary MOF-based materials for metal-sulfur batteries. • Fe/Zr binary UiO-66(Fe/Zr)-NH 2 was synthesized to modify Li-S ba...