Halide-free and metal-free allylic thiolation/selenation of P(O)H compounds with sulfur/selenium and allylic alcohols

作者：Longzhi Zhu, Weiwei Luo, Furong Guo, Lin Chen, Ying Tang, Biquan Xiong, Yu Liu, Kewen Tang, Renhua Qiu · 发表于：Green Chemistry · 年份：2024 · DOI：10.1039/d4gc03960b · 被引用次数：25 · 研究领域：Sulfur-Based Synthesis Techniques、Chemical Synthesis and Reactions、Catalytic C–H Functionalization Methods

A halide- and metal-free method for forming C–S/Se–P(O) bonds using allylic alcohols, P(O)H compounds, and elemental sulfur/selenium is reported, eliminating the need for toxic, odorous, and moisture-sensitive starting materials.