Investigation of the Dual‐Regulatory Mechanism of Zr in MnRE1‐xZrxO2+δ Oxide Catalysts for NO Oxidation

作者：Zihao Xu, Dongming Chen, Rui Chen, Ziteng Mao, Zheng Zhao, Yongqi Zhang, Meisheng Cui, Yongke Hou, Chong Han, Juanyu Yang, Xiaowei Huang · 发表于：Small · 年份：2024 · DOI：10.1002/smll.202405740 · 被引用次数：5 · 研究领域：Catalytic Processes in Materials Science、Catalysis and Oxidation Reactions、Advanced Photocatalysis Techniques

Abstract Utilizing Diesel Oxidation Catalysts (DOC) to partially oxidize NO to NO 2 is a crucial step in controlling NO x emissions from diesel engines. However, enhancing both catalytic activity and hydrothermal stability remains a significant challenge. Benefiting from abundant asymmetric oxygen vacancies and increased Mn 4+ content, MnRE 0.5 Zr 0.5 exhibits superior NO oxidation performance (T 63 = 337 °C) and hydrothermal aging resistance (T 52 = 340 °C) compared to the undoped sample (T 53 = 365 °C). XPS, Raman, TPR, and XAS are employed to verify the elevation of oxygen vacancy concentration and Mn valence state modulation due to Zr introduction. Furthermore, compared to MnRE (1.36 eV), the formation energy of oxygen vacancies in MnRE 0.5 Zr 0.5 is significantly reduced (0.17 eV). This work elucidates the dual regulatory role of Zr in the Mn‐RE‐Zr ternary system, providing theoretical support and guidance for the design of catalysts for atmospheric pollutant purification and industrial catalysis.