Double‐Walled Honeycomb‐Like Metal‐Organophosphonium Framework with High H 2 Gas Adsorption Capacities

作者：Sa-Sa Xia, Lan Li, Chen‐Hao Bao, Xusheng Wang, Zhi Chen · 发表于：European Journal of Inorganic Chemistry · 年份：2024 · DOI：10.1002/ejic.202400430 · 被引用次数：3 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Advanced NMR Techniques and Applications

Abstract This study successfully synthesized a new Metal‐Organic Framework (MOF) named CJLU−L2, which was constructed from phosphorus‐containing ligands and Co(II) ions. The structure revealed through single‐crystal X‐ray diffraction (SCXRD), features a double‐walled honeycomb‐shaped structure with a one‐dimensional channel of ~6.5 Å. According to the PLATON calculation, the pore volume per unit cell of CJLU−L2 was determined to be 6825.0 Å 3 , constituting 57.5 % of the total crystal volume (11874.9 Å 3 ). The Brunauer‐Emmett‐Teller (BET) surface area of CJLU−L2 was determined to be 954 m 2 /g by N 2 adsorption measurement at 77 K. The phase purity of CJLU−L2 was verified by powder X‐ray diffraction (PXRD) and infrared spectroscopy (IR), while its thermal stability was confirmed by thermogravimetric analysis (TGA). Hydrogen adsorption experiments demonstrate that CJLU−L2 exhibits a high hydrogen adsorption capacity, indicating significant potential for gas adsorption applications.