Exclusive generation of a superoxide radical by a porous aromatic framework for fast photocatalytic decontamination of mustard gas simulant in room air

作者：Jian Song, Hengtao Lei, Yuhui Zhai, Zilong Dou, Yongyue Ding, Xueyan Han, Fengchao Cui, Yuyang Tian, Guangshan Zhu · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d4sc04551c · 被引用次数：20 · 研究领域：Covalent Organic Framework Applications、Metal-Organic Frameworks: Synthesis and Applications、Luminescence and Fluorescent Materials

Photoactive PAF-68 was used to specifically initiate superoxide anion as the reactive oxygen species for oxidative degradation, showing rapid degradation ability towards the mustard gas simulant CEES in room air, as fast as in pure oxygen.