High-efficiency C3 electrosynthesis on a lattice-strain-stabilized nitrogen-doped Cu surface

作者：Wenzhe Niu, Jie Feng, Junfeng Chen, Lei Deng, Wen Guo, Huajing Li, Liqiang Zhang, Youyong Li, Bo Zhang · 发表于：Nature Communications · 年份：2024 · DOI：10.1038/s41467-024-51478-4 · 被引用次数：40 · 研究领域：CO2 Reduction Techniques and Catalysts、Electrocatalysts for Energy Conversion、Semiconductor materials and devices

The synthesis of multi-carbon (C2+) fuels via electrocatalytic reduction of CO, H2O using renewable electricity, represents a significant stride in sustainable energy storage and carbon recycling. The foremost challenge in this field is the production of extended-chain carbon compounds (Cn, n ≥ 3), wherein elevated *CO coverage (θco) and its subsequent multiple-step coupling are both critical. Notwithstanding, there exists a “seesaw” dynamic between intensifying *CO adsorption to augment θco and surmounting the C-C coupling barrier, which have not been simultaneously realized within a singular catalyst yet. Here, we introduce a facilely synthesized lattice-strain-stabilized nitrogen-doped Cu (LSN-Cu) with abundant defect sites and robust nitrogen integration. The low-coordination sites enhance θco and concurrently, the compressive strain substantially fortifies nitrogen dopants on the catalyst surface, promoting C-C coupling activity. The n-propanol formation on the LSN-Cu electrode exhibits a 54% faradaic efficiency and a 29% half-cell energy efficiency. Moreover, within a membrane electrode assembly setup, a stable n-propanol electrosynthesis over 180 h at a total current density of 300 mA cm−2 is obtained. The transformation of CO and H2O into C2+ fuels using renewable electricity represents a significant stride in carbon recycling. Here, the authors introduce a plasma-treated Cu catalyst, achieving high CO coverage and promoted C-C coupling ability for efficient n-propano...