Counterion Distribution in the Stern Layer on Charged Surfaces

作者：Tianyi Han, Wanxing Xu, Jie Han, Vahid Adibnia, Hongjiang He, Chenhui Zhang, Jianbin Luo · 发表于：Nano Letters · 年份：2024 · DOI：10.1021/acs.nanolett.4c01230 · 被引用次数：11 · 研究领域：Electrostatics and Colloid Interactions、Electrochemical Analysis and Applications、Spectroscopy and Quantum Chemical Studies

Counterion adsorption at the solid-liquid interface affects numerous applications. However, the counterion adsorption density in the Stern layer has remained poorly evaluated. Here we report the direct determination of surface charge density at the shear plane between the Stern layer and the diffuse layer. By the Grahame equation extension and streaming current measurements for different solid surfaces in different aqueous electrolytes, we are able to obtain the counterion adsorption density in the Stern layer, which is mainly related to the surface charge density but is less affected by the bulk ion concentration. The charge inversion concentration is further found to be sensitive to the ion type and ion valence rather than to the charged surface, which is attributed to the ionic competitive adsorption and ion-ion correlations. Our findings offer a framework for understanding ion distribution in many physical and chemical processes where the Stern layer is ubiquitous.