Self‐Calibrated Thermometer and Dynamic Anti‐Counterfeiting Based on YNbO 4 :Pr 3+ Luminescent Material

作者：Yuqi Chen, Fangyi Zhao, Kangrui Qiang, Qinan Mao, Heyi Yang, Yiwen Zhu, Meijiao Liu, Jiasong Zhong · 发表于：Advanced Optical Materials · 年份：2024 · DOI：10.1002/adom.202401688 · 被引用次数：63 · 研究领域：Luminescence Properties of Advanced Materials、Luminescence and Fluorescent Materials、Perovskite Materials and Applications

Abstract Phosphors with multifunctional applications have attracted extensive research, especially in thermometer and anti‐counterfeiting fields. Herein, a series of Pr 3+ ‐doped YNbO 4 (YNO) phosphors with adjustable photoluminescence and red persistent luminescence (PersL) performances are developed. YNO host exhibits the blue self‐activated luminescence, and the different Pr 3+ emission peaks possess various thermal stability properties due to the thermal quenching channel generated by the intervalence charge transfer state between Pr 3+ and Nb 5+ ions. Two kinds of fluorescence intensity ratio models with high absolute and relative sensitivities are realized to measure the temperature under dual‐wavelength excitation. Moreover, YNO:Pr 3+ exhibits the red PersL with a duration of about 120 s upon ceasing the UV excitation light source. The fabricated YNO:Pr 3+ ‐polydimethylsiloxane films display different luminescence patterns with the passage of time after turning off UV light, which can cleverly achieve dynamic conversion. These results demonstrate that YNO:Pr 3+ phosphor has potential applications in dual‐wavelength excited thermometry and dynamic anti‐counterfeiting fields.