Visible light-promoted defluorinative alkylation/arylation of α-trifluoromethyl alkenes with thianthrenium salts

作者：Yue Zhang, Jianyou Mao, Zhihong Wang, Liang‐Fu Tang, Zhijin Fan · 发表于：Green Chemistry · 年份：2024 · DOI：10.1039/d4gc02901a · 被引用次数：25 · 研究领域：Fluorine in Organic Chemistry、Radical Photochemical Reactions、Catalytic C–H Functionalization Methods

Defluorinative alkylation and arylation between thianthrenium salts and α-trifluoromethyl alkene to afford gem -difluoroolefins by easily recycling thianthrene under visible light irradiation and free of metal photocatalyst.