Chiral 3D Perovskite Formation Induced by Chiral Templates

作者：Han-Jiang Yang, Bingxuan Li, Jin-Yun Wang, Liang‐Jin Xu, Zhong‐Ning Chen · 发表于：Nano Letters · 年份：2024 · DOI：10.1021/acs.nanolett.4c02125 · 被引用次数：29 · 研究领域：Perovskite Materials and Applications、Advanced Condensed Matter Physics、Magnetic and transport properties of perovskites and related materials

Chiral 3D perovskites pose challenges compared to lower-dimensional variants due to limited chiral organic cation options. Here, we present a universal and controlled method for synthesizing chiral 3D lead halide perovskites using organic amines or alcohols as chiral templates. Introducing these templates to PbCl 2 in N, N -dimethylformamide (DMF) under acidic conditions induces the crystallization of R/S [DMA]PbCl 3 (DMA = dimethylamine). The resulting structure aligns with the templates used, stemming from the helical Pb 2 Cl 9 5– chain as verified by single-crystal X-ray diffraction. Furthermore, the chiral perovskite exhibits absorption and circular dichroism (CD) signals in the high-energy band, enabling the circularly polarized light (CPL) detection in the UV spectrum. A CPL detector constructed by this chiral perovskite demonstrates excellent performance, boasting an anisotropy factor for photocurrent ( g Iph ) of 0.296. Our work not only introduces a novel and controllable method for crafting chiral perovskites but also opens new avenues for circularly polarized light detection.