Interlaboratory Comparison of Branched GDGT Temperature and pH Proxies Using Soils and Lipid Extracts

作者：Cindy De Jonge, Francien Peterse, Klaas G.J. Nierop, Thomas M. Blattmann, Marcelo R. Alexandre, Salomé Ansanay-Alex, T. Al Austin, Mathieu Babin, Édouard Bard, Thorsten Bauersachs, Jerome Blewett, Brenna Boehman, Isla S. Castañeda, Junhui Chen, Martina Conti, Sergio Contreras, Julia Cordes, Nina Davtian, Bart E. van Dongen, Bella Duncan, Felix J. Elling, Valier Galy, S. Gao, Jens Hefter, Kai‐Uwe Hinrichs, Mitchell R. Helling, Mariska Hoorweg, Ellen C. Hopmans, Juzhi Hou, Yongsong Huang, Arnaud Huguet, Guodong Jia, Cornelia Karger, Brendan J. Keely, Stephanie Kusch, Hui Li, Jie Liang, Julius S. Lipp, Weiguo Liu, Hongxuan Lu, Kai Mangelsdorf, Hayley Manners, Alfredo Martinez Garcia, Guillemette Ménot, Gesine Mollenhauer, B. David A. Naafs, Sebastian Naeher, Lauren K. O’Connor, E. M. Pearce, Ann Pearson, Zhiguo Rao, Marta Rodrigo‐Gámiz, Chris Rosendahl, Frauke Rostek, Rui Bao, Prasanta Sanyal, Florence Schubotz, Wesley Scott, Rahul Sen, Appy Sluijs, Rienk H. Smittenberg, Ioana C. Stefanescu, Jia‐Tao Sun, Paul Sutton, Jess Tierney, E. Tejos, Joan Villanueva, Huanye Wang, Josef P. Werne, Masanobu Yamamoto, Huan Yang, Aifeng Zhou · 发表于：Geochemistry Geophysics Geosystems · 年份：2024 · DOI：10.1029/2024gc011583 · 被引用次数：15 · 研究领域：Geology and Paleoclimatology Research、Isotope Analysis in Ecology、Groundwater and Isotope Geochemistry

Abstract Ratios of glycerol dialkyl glycerol tetraethers (GDGT), which are membrane lipids of bacteria and archaea, are at the base of several paleoenvironmental proxies. They are frequently applied to soils as well as lake‐ and marine sediments to generate records of past temperature and soil pH. To derive meaningful environmental information from these reconstructions, high analytical reproducibility is required. Based on submitted results by 39 laboratories from across the world, which employ a diverse range of analytical and quantification methods, we explored the reproducibility of brGDGT‐based proxies (MBT′ 5ME , IR, and #rings tetra ) measured on four soil samples and four soil lipid extracts. Correct identification and integration of 5‐ and 6‐methyl brGDGTs is a prerequisite for the robust calculation of proxy values, but this can be challenging as indicated by the large inter‐interlaboratory variation. The exclusion of statistical outliers improves the reproducibility, where the remaining uncertainty translates into a temperature offset from median proxy values of 0.3–0.9°C and a pH offset of 0.05–0.3. There is no apparent systematic impact of the extraction method and sample preparation steps on the brGDGT ratios. Although reported GDGT concentrations are generally consistent within laboratories, they vary greatly between laboratories. This large variability in brGDGT quantification may relate to variations in ionization efficiency or specific mass spectrometer sett...