Photoinduced Ordered Growth of Copper-Doped Polyaniline Nanotubes: A Method to Improve the Catalytic Activity for C–N Coupling Reactions

作者：Ying Chen, Yiyang Zhang, Hongwei Zhou, Lei Yu · 发表于：ACS Applied Materials & Interfaces · 年份：2024 · DOI：10.1021/acsami.4c05028 · 被引用次数：9 · 研究领域：Covalent Organic Framework Applications、Advanced Photocatalysis Techniques、Conducting polymers and applications

Polyaniline-supported metal nanoparticles (M@PANIs) have been widely employed as catalysts for organic reactions. Traditionally, the catalytic activities of the materials can be improved by introducing functional groups onto the aniline monomers, but it may enhance the catalyst cost and reduce the production yield of the material. This work reports a new strategy for improving the catalytic activity of M@PANIs. It was found that induced by visible light in the presence of a polymeric carbon nitride catalyst and copper dopant, the oxidative polymerization of simple aniline occurred slowly and orderly to produce the copper-doped polyaniline nanotubes. The unique tubular structure protected the catalytically active Cu(I) inside and endowed even more sufficient contact of the catalytic sites with reactants so that the material exhibited excellent catalytic performances in C-N coupling reactions.