NiO/RuO 2 p–n Heterojunction Nanofoam as a High-Performance Electrocatalyst for Desulfurization and Concurrent Hydrogen Evolution

作者：Hao Wu, Cong Wang, Yujie Ma, Sirui Huang, Yilun Ren, Fan Ding, Fengqi Li, Yurong Yang, Jian Gu, Shaochun Tang, Xiangkang Meng · 发表于：Inorganic Chemistry · 年份：2024 · DOI：10.1021/acs.inorgchem.4c01684 · 被引用次数：19 · 研究领域：Electrocatalysts for Energy Conversion、Advanced Photocatalysis Techniques、Advanced battery technologies research

The development of bifunctional electrocatalysts with excellent performance in both the hydrogen evolution reaction (HER) and sulfide oxidation reaction (SOR) remains a formidable challenge. Herein, we experimentally synthesize a NiO/RuO 2 p–n heterojunction nanofoam that exhibits highly desirable electrocatalytic properties for both the HER and the SOR. We further design an electrolytic cell by pairing alkaline HER with SOR utilizing the NiO/RuO 2 heterojunction nanofoam as both the anode and the cathode, which demands a low applied voltage of 0.846 V to achieve a current density of 10 mA cm –2 . Density functional theory calculations confirm that the formation of the NiO/RuO 2 p–n heterojunction nanofoam effectively regulates the electronic structure, thereby boosting the electrocatalytic performances for both HER and SOR. This work not only provides a novel strategy to prepare an efficient and stable nanofoam electrocatalyst for hydrogen production but also highlights the potential application of oxide heterojunction electrocatalysts in treating sulfur-containing waste liquid.