Kinetics of sulfur-transfer from titanocene (poly)sulfides to sulfenyl chlorides: rapid metal-assisted concerted substitution

作者：Pedro H. Helou de Oliveira, Patrick J. Boaler, Guoxiong Hua, Nathan M. West, Robert T. Hembre, Jonathan M. Penney, Malik H. Al‐Afyouni, J. Derek Woollins, Andrés García‐Domínguez, Guy C. Lloyd‐Jones · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d4sc02737j · 被引用次数：4 · 研究领域：Sulfur-Based Synthesis Techniques、Chemical Synthesis and Reactions、Synthesis and Catalytic Reactions

The mechanism has been investigated by stopped-flow UV-Vis/NMR, titrations, numerical kinetic modelling and KS-DFT calculations.