Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: structure–function relationships

作者：Xingyu Lu, Qi Ke, Xueya Dai, Yunlong Li, Di Wang, Jing Dou, Wei Qi · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d4sc01752h · 被引用次数：22 · 研究领域：Supercapacitor Materials and Fabrication、Catalysis for Biomass Conversion、Polyoxometalates: Synthesis and Applications

linking the activity to structural compositions of PANI; both polaronic-type nitrogen (N3) and positively charged nitrogen (N4) species are proved responsible for adsorption and activation of HMF, and the intrinsic activity of N4 is higher than that of N3. The present work provides new physical-chemical insights into the mechanism of the HMFOR on non-metallic catalysts, paving the way for the establishment of structure-function relations and further development of novel electrochemical synthesis systems.