Chlorido[5,10,15,20-tetrakis(quinoline-7-carboxamido)porphinato]iron(III)

作者：Jun Yang, Cuijuan Zhang, Jiaxiang Chu · 发表于：IUCrData · 年份：2024 · DOI：10.1107/s2414314624004966 · 研究领域：Porphyrin and Phthalocyanine Chemistry、Metal-Catalyzed Oxygenation Mechanisms、Lanthanide and Transition Metal Complexes

cation (site symmetry 2) is coordinated in a fivefold manner, with four pyrrole N atoms of the porphyrin core in the basal sites and one Cl atom (site symmetry 2) in the apical position, which completes a slightly distorted square-pyramidal environment. The porphyrin macrocycle shows a characteristic ruffled-shape distortion and the iron atom is displaced out of the porphyrin plane by 0.42 Å with the average Fe-N distance being 2.054 (4) Å; the Fe-Cl bond length is 2.2042 (7) Å. Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds occur in the crystal structure.