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Synthesis of ( E )-vinyl sulfides via copper-catalyzed hydrothiolation of internal alkynes with thiosulfonates and silanes

作者:Ming-Hui Gao, Jingyu Li, Long Chen, Zhen Qin, Weijie Wang, Wei Dong, Mingyan Liu, Xiulian Zhang, Chuanzhou Tao · 发表于:Organic Chemistry Frontiers · 年份:2024 · DOI:10.1039/d4qo00448e · 被引用次数:4 · 研究领域:Sulfur-Based Synthesis Techniques、Cyberloafing and Workplace Behavior、Chemical Synthesis and Reactions

A copper-catalyzed syn -hydrothiolation of internal alkynes with thiosulfonates and silanes has been disclosed, which offers regio- and stereoselective access to ( E )-vinyl sulfides.