Amorphous FeSnO x Nanosheets with Hierarchical Vacancies for Room‐Temperature Sodium‐Sulfur Batteries

作者：Wu Sun, Junyu Hou, Junyu Hou, Yunlei Zhou, Tianke Zhu, Qunyao Yuan, Shaolei Wang, Farid Manshaii, Changsheng Song, Xingyu Lei, Xiaoyan Wu, Hern Kim, Yi Yu, Chuanxiao Xiao, Hongjun Zhang, Yun Song, Dalin Sun, Binbin Jia, Binbin Jia, Guangmin Zhou, Guangmin Zhou, Jie Zhao · 发表于：Angewandte Chemie International Edition · 年份：2024 · DOI：10.1002/anie.202404816 · 被引用次数：35 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Advanced battery technologies research

Abstract Room‐temperature sodium‐sulfur (RT Na−S) batteries, noted for their low material costs and high energy density, are emerging as a promising alternative to lithium‐ion batteries (LIBs) in various applications including power grids and standalone renewable energy systems. These batteries are commonly assembled with glass fiber membranes, which face significant challenges like the dissolution of polysulfides, sluggish sulfur conversion kinetics, and the growth of Na dendrites. Here, we develop an amorphous two‐dimensional (2D) iron tin oxide (A‐FeSnO x ) nanosheet with hierarchical vacancies, including abundant oxygen vacancies (O v s) and nano‐sized perforations, that can be assembled into a multifunctional layer overlaying commercial separators for RT Na−S batteries. The O v s offer strong adsorption and abundant catalytic sites for polysulfides, while the defect concentration is finely tuned to elucidate the polysulfides conversion mechanisms. The nano‐sized perforations aid in regulating Na ions transport, resulting in uniform Na deposition. Moreover, the strategic addition of trace amounts of Ti 3 C 2 (MXene) forms an amorphous/crystalline (A/C) interface that significantly improves the mechanical properties of the separator and suppresses dendrite growth. As a result, the task‐specific layer achieves ultra‐light (~0.1 mg cm −2 ), ultra‐thin (~200 nm), and ultra‐robust (modulus=4.9 GPa) characteristics. Consequently, the RT Na−S battery maintained a high capacity o...