Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks

作者：Marco Daturi, Vanessa Blasin‐Aubé, Ji Wong Yoon, Philippe Bazin, Alexandré Vimont, Jong‐San Chang, Young Kyu Hwang, You‐Kyong Seo, Seunghun Jang, Hyunju Chang, Stefan Wuttke, Patricia Horcajada, Masaaki Haneda, Christian Serre · 发表于：Advanced Materials · 年份：2024 · DOI：10.1002/adma.202403053 · 被引用次数：13 · 研究领域：Catalytic Processes in Materials Science、Metal-Organic Frameworks: Synthesis and Applications、Mercury impact and mitigation studies

Abstract Nitrogen oxides represent one of the main threats for the environment. Despite decades of intensive research efforts, a sustainable solution for NO x removal under environmental conditions is still undefined. Using theoretical modelling, material design, state‐of‐the‐art investigation methods and mimicking enzymes, it is found that selected porous hybrid iron(II/III) based MOF material are able to decompose NO x , at room temperature, in the presence of water and oxygen, into N 2 and O 2 and without reducing agents. This paves the way to the development of new highly sustainable heterogeneous catalysts to improve air quality.