Boosting Electrochemical Nitrogen Reduction via Axial Coordination Engineering on Single‐Iron‐Atom Catalysts

作者：Yang Yang, Hanlin Wang, Xuehai Tan, Keren Jiang, Shengli Zhai, Yifan Li, Xuesong Xie, Ning Chen, Hao Zhang, Zhi Li · 发表于：Advanced Functional Materials · 年份：2024 · DOI：10.1002/adfm.202403535 · 被引用次数：56 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Advanced Photocatalysis Techniques、Nanomaterials for catalytic reactions

Abstract Electrocatalytic nitrogen (N 2 ) reduction reaction (NRR) presents a sustainable alternative to the Haber–Bosch process for ammonia (NH 3 ) synthesis. Iron phthalocyanine (FePc) is demonstrated as a promising catalyst for the electrocatalytic NRR. However, FePc with planar symmetric Fe‐N 4 sites exhibits poor N 2 adsorption and activation capabilities, resulting in an unsatisfactory NRR performance. Herein, an axial oxygen coordination strategy is developed to optimize the local electron distribution on FePc for improving N 2 adsorption and activation. The as‐obtained FePc‐O‐CP shows a superior NH 3 yield rate (59.72 µg h −1 mg −1 cat. ) and a considerable Faradaic efficiency (13.76%) in 0.1 m HCl. Density functional theory (DFT) calculations verify that the axial oxygen ligand on FePc inhibits the adsorption of H + and enhances the N 2 adsorption and activation, thereby greatly promoting NH 3 generation. This work reveals the significance of regulating the local coordination environment of single‐atom catalysts for improving electrocatalytic NRR performance and provides a feasible strategy for the rational design of atomic‐scale active sites.