Photosensitizing metal covalent organic framework with fast charge transfer dynamics for efficient CO 2 photoreduction

作者：Wang‐Kang Han, Jiayu Li, Ruo‐Meng Zhu, Min Wei, Shilin Xia, Jiaxing Fu, Jinfang Zhang, Huan Pang, Ming‐De Li, Zhi‐Guo Gu · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d4sc01896f · 被引用次数：25 · 研究领域：Advanced Photocatalysis Techniques、Covalent Organic Framework Applications、Perovskite Materials and Applications

and 97.7% selectivity. The femtosecond transient absorption spectroscopy combined with theoretical calculations uncovered the fast charge-transfer dynamics occurring between the photoactive and catalytic centers, providing a comprehensive understanding of the photocatalytic mechanism. This work offers in-depth insight into the design of MCOF-based photocatalysts for solar energy utilization.