NHC/B(OH) 3 -mediated C3-selective acylation of unprotected monosaccharides: mechanistic insights and toward simpler/greener solutions

作者：Jiamiao Jin, Jiangtao Guo, Feng Xu, Ya Lv, Guanjie Wang, Jia Song, Wen‐Xin Lv, Tingting Li, Yonggui Robin · 发表于：Green Chemistry · 年份：2024 · DOI：10.1039/d3gc05005j · 被引用次数：7 · 研究领域：N-Heterocyclic Carbenes in Organic and Inorganic Chemistry、Carbohydrate Chemistry and Synthesis、Chemical Synthesis and Analysis

A simple and greener protocol for the regio-selective acylation of unprotected monosaccharides is achieved using boric acid as a promoter and N -heterocyclic carbene as an organic catalyst.