Two-dimensional lead halide perovskite lateral homojunctions enabled by phase pinning

作者：Huilong Hong, Songhao Guo, Leyang Jin, Yuhong Mao, Yuguang Chen, Jiazhen Gu, Shaochuang Chen, Xu Huang, Yan Guan, Xiaotong Li, Yan Li, Xujie Lü, Yongping Fu · 发表于：Nature Communications · 年份：2024 · DOI：10.1038/s41467-024-47406-1 · 被引用次数：42 · 研究领域：Perovskite Materials and Applications、Solid-state spectroscopy and crystallography、Quantum Dots Synthesis And Properties

Abstract Two-dimensional organic-inorganic hybrid halide perovskites possess diverse structural polymorphs with versatile physical properties, which can be controlled by order-disorder transition of the spacer cation, making them attractive for constructing semiconductor homojunctions. Here, we demonstrate a space-cation-dopant-induced phase stabilization approach to creating a lateral homojunction composed of ordered and disordered phases within a two-dimensional perovskite. By doping a small quantity of pentylammonium into (butylammonium) 2 PbI 4 or vice versa, we effectively suppress the ordering transition of the spacer cation and the associated out-of-plane octahedral tilting in the inorganic framework, resulting in phase pining of the disordered phase when decreasing temperature or increasing pressure. This enables epitaxial growth of a two-dimensional perovskite homojunction with tunable optical properties under temperature and pressure stimuli, as well as directional exciton diffusion across the interface. Our results demonstrate a previously unexplored strategy for constructing two-dimensional perovskite heterostructures by thermodynamic tuning and spacer cation doping.