Photoinduced decatungstate-catalyzed C(sp 3 )–H thioetherification by sulfinate salts

作者：Pengcheng Li, Jia‐Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang, Wujiong Xia · 发表于：Organic & Biomolecular Chemistry · 年份：2024 · DOI：10.1039/d4ob00394b · 被引用次数：10 · 研究领域：Sulfur-Based Synthesis Techniques、Chemical Synthesis and Reactions、Polyoxometalates: Synthesis and Applications

Thiols and thioesters play crucial roles in pharmaceuticals, biology, and material science as essential organosulfur compounds. Leveraging readily available and cost-effective inert alkanes through direct thioetherification holds promise for yielding high-value-added products. Herein, we present a photoinduced strategy for sulfur-containing modification of inert alkanes utilizing decatungstate as hydrogen atom transfer reagent, offering a straightforward and practical approach for synthesizing thioethers and thioesters.