An efficient approach toward production of near-zigzag single-chirality carbon nanotubes

作者：Yahan Li, Linhai Li, Hua Jiang, Qian Liu, Maoshuai He, Duanliang Zhou, Kaili Jiang, Huaping Liu, Xiaofan Qin, Y Gao, Qianru Wu, Xinyan Chi, Zhibo Li, Jin Zhang · 发表于：Science Advances · 年份：2024 · DOI：10.1126/sciadv.adn6519 · 被引用次数：31 · 研究领域：Carbon Nanotubes in Composites、Graphene research and applications、Supercapacitor Materials and Fabrication

Synthesizing single-walled carbon nanotubes (SWCNTs) with a narrow chirality distribution is essential for obtaining pure chirality materials through postgrowth sorting techniques. Using carbon monoxide chemical vapor deposition, we devise a ruthenium (Ru) catalyst supported by silica for the bulk production of SWCNTs containing only a few ( n , m ) species. The result is attributed to the limited carbon dissociation on the supported Ru clusters, favoring the growth of only small-diameter SWCNTs at comparable growth rates. The resulting materials expedite high-purity single chirality separation using gel chromatography, leading to unprecedented yields of 3.5% for (9, 1) and 5.2% for (9, 2) nanotubes, which surpass those separated from HiPco SWCNTs by two orders of magnitude. This work sheds light on the large-quantity synthesis of SWCNTs with enriched species beyond near-armchair ones for their high-yield separation.