Ag 1+ incorporation via a Zr 4+ -anchored metalloligand: fine-tuning catalytic Ag sites in Zr/Ag bimetallic clusters for enhanced eCO 2 RR-to-CO activity

作者：Liangjun Li, Wen-Lei Mu, Yi-Qi Tian, Wei‐Dong Yu, Lan-Yan Li, Jun Yan, Chao Liu · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d3sc07005k · 被引用次数：19 · 研究领域：Nanocluster Synthesis and Applications、CO2 Reduction Techniques and Catalysts、Carbon dioxide utilization in catalysis

We employed three structurally closely-related Zr/Ag bimetallic nanoclusters as model catalysts to conduct a precise comparison of the catalytic activity of three distinct Ag sites in CO 2 electroreduction at the molecular level.