Fluorine Chemistry in Rechargeable Batteries: Challenges, Progress, and Perspectives

作者：Yao Wang, Xu Yang, Yuefeng Meng, Zuxin Wen, Ran Han, Xia Hu, Bing Sun, Feiyu Kang, Baohua Li, Dong Zhou, Chunsheng Wang, Guoxiu Wang · 发表于：Chemical Reviews · 年份：2024 · DOI：10.1021/acs.chemrev.3c00826 · 被引用次数：236 · 研究领域：Advanced Battery Materials and Technologies、Inorganic Fluorides and Related Compounds、Advancements in Battery Materials

The renewable energy industry demands rechargeable batteries that can be manufactured at low cost using abundant resources while offering high energy density, good safety, wide operating temperature windows, and long lifespans. Utilizing fluorine chemistry to redesign battery configurations/components is considered a critical strategy to fulfill these requirements due to the natural abundance, robust bond strength, and extraordinary electronegativity of fluorine and the high free energy of fluoride formation, which enables the fluorinated components with cost effectiveness, nonflammability, and intrinsic stability. In particular, fluorinated materials and electrode|electrolyte interphases have been demonstrated to significantly affect reaction reversibility/kinetics, safety, and temperature tolerance of rechargeable batteries. However, the underlining principles governing material design and the mechanistic insights of interphases at the atomic level have been largely overlooked. This review covers a wide range of topics from the exploration of fluorine-containing electrodes, fluorinated electrolyte constituents, and other fluorinated battery components for metal-ion shuttle batteries to constructing fluoride-ion batteries, dual-ion batteries, and other new chemistries. In doing so, this review aims to provide a comprehensive understanding of the structure-property interactions, the features of fluorinated interphases, and cutting-edge techniques for elucidating the role of f...