Combination of dimensional reduction and active site addition strategies for preparing unique {RE 9 }-cluster-based MOFs: efficient CO 2 fixation and Knoevenagel condensation

作者：Ying Zhao, Dan Wu, Yidan Qiao, Guo‐Ping Yang, Lu‐Fang Ma, Yao‐Yu Wang · 发表于：Inorganic Chemistry Frontiers · 年份：2024 · DOI：10.1039/d3qi02527f · 被引用次数：43 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Carbon dioxide utilization in catalysis、Inorganic Fluorides and Related Compounds

A series of 2D {RE 9 }-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO 2 fixation and Knoevenagel condensation under mild conditions.