An efficient photothermal conversion material based on D‐A type luminophore for solar‐driven desalination

作者：Jun‐Cheng Yang, Lin Wu, Le Wang, Runhua Ren, Pu Chen, Chunxuan Qi, Hai‐Tao Feng, Ben Zhong Tang · 发表于：Aggregate · 年份：2024 · DOI：10.1002/agt2.535 · 被引用次数：59 · 研究领域：Solar-Powered Water Purification Methods、Surface Modification and Superhydrophobicity、Membrane Separation Technologies

Abstract Solar‐driven interfacial evaporation is a promising technology for desalination. The photothermal conversion materials are at the core and play a key role in this field. Design of photothermal conversion materials based on organic dyes for desalination is still a challenge due to lack of efficient guiding strategy. Herein, a new D (donor)‐A (acceptor) type conjugated tetraphenylpyrazine (TPP) luminophore (namely TPP‐2IND) was prepared as a photothermal conversion molecule. It exhibited a broad absorption spectrum and strong π – π stacking in the solid state, resulting in efficient sunlight harvesting and boosting nonradiative decay. TPP‐2IND powder exhibited high photothermal efficiency upon 660 nm laser irradiation (0.9 W cm −2 ), and the surface temperature can reach to 200°C. Then, an interfacial heating system based on TPP‐2IND is established successfully. The water evaporation rate and the solar‐driven water evaporation efficiency were evaluated up to 1.04 kg m −2 h −1 and 65.8% under 1 sunlight, respectively. Thus, this novel solar‐driven heating system shows high potential for desalination and stimulates the development of advanced photothermal conversion materials.