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Copper-catalyzed oxidative cyclization of 2-(1 H -pyrrol-1-yl)aniline and alkylsilyl peroxides: a route to pyrrolo[1,2- a ]quinoxalines

作者:Zhenyu An, Man Miao, Fengkai Sun, Xiaobing Lan, Jianqiang Yu, Xiaoli Guo, Jian Zhang · 发表于:Organic & Biomolecular Chemistry · 年份:2024 · DOI:10.1039/d3ob01934a · 被引用次数:8 · 研究领域:Synthesis and Biological Evaluation、Synthesis and Characterization of Pyrroles、Catalytic C–H Functionalization Methods

-pyrrol-1-yl)anilines and alkylsilyl peroxides. This reaction proceeds through C-C bond cleavage and new C-C and C-N bond formation. A mechanistic study suggests that alkyl radical species participate in the cascade reaction.