A universal and scalable transformation of bulk metals into single-atom catalysts in ionic liquids

作者：Shujuan Wang, Ming‐Hui Lu, Xuewen Xia, Fei Wang, Xiaolu Xiong, Kai Ding, Zhongya Pang, Guangshi Li, Qian Xu, Hsien‐Yi Hsu, Shen Hu, Ji Li, Yufeng Zhao, Jing Wang, Xingli Zou, Xionggang Lu · 发表于：Proceedings of the National Academy of Sciences · 年份：2024 · DOI：10.1073/pnas.2319136121 · 被引用次数：9 · 研究领域：Ionic liquids properties and applications、Catalytic Processes in Materials Science、Electrocatalysts for Energy Conversion

Single-atom catalysts (SACs) with maximized metal atom utilization and intriguing properties are of utmost importance for energy conversion and catalysis science. However, the lack of a straightforward and scalable synthesis strategy of SACs on diverse support materials remains the bottleneck for their large-scale industrial applications. Herein, we report a general approach to directly transform bulk metals into single atoms through the precise control of the electrodissolution–electrodeposition kinetics in ionic liquids and demonstrate the successful applicability of up to twenty different monometallic SACs and one multimetallic SAC with five distinct elements. As a case study, the atomically dispersed Pt was electrodeposited onto Ni 3 N/Ni-Co-graphene oxide heterostructures in varied scales (up to 5 cm × 5 cm) as bifunctional catalysts with the electronic metal–support interaction, which exhibits low overpotentials at 10 mA cm −2 for hydrogen evolution reaction (HER, 30 mV) and oxygen evolution reaction (OER, 263 mV) with a relatively low Pt loading (0.98 wt%). This work provides a simple and practical route for large-scale synthesis of various SACs with favorable catalytic properties on diversified supports using alternative ionic liquids and inspires the methodology on precise synthesis of multimetallic single-atom materials with tunable compositions.