Ligand-controlled exposure of active sites on the Pd 1 Ag 14 nanocluster surface to boost electrocatalytic CO 2 reduction

作者：Along Ma, Yonggang Ren, Yang Zuo, Jiawei Wang, Shutong Huang, Xiaoshuang Ma, Shuxin Wang · 发表于：Chemical Communications · 年份：2024 · DOI：10.1039/d4cc00152d · 被引用次数：13 · 研究领域：Nanocluster Synthesis and Applications、Quantum Dots Synthesis And Properties、Advanced Nanomaterials in Catalysis

Two nanoclusters, Pd 1 Ag 14 -S and Pd 1 Ag 14 -E , were synthesized, with the latter exposing an Ag active site. eCO 2 RR studies showed this exposure markedly improves catalytic selectivity for converting CO 2 to CO.