Reactivity of cationic silver clusters with O 2 : a probe of interplay between clusters’ geometric and electronic structures

作者：Jin Hu, Jun Ma, Zhengqian Jin, Wen Liu, Lulu Huang, Xuefeng Wang, Xiaopeng Xing · 发表于：Physical Chemistry Chemical Physics · 年份：2024 · DOI：10.1039/d3cp05082c · 被引用次数：6 · 研究领域：Catalytic Processes in Materials Science、Nanocluster Synthesis and Applications、Advanced Chemical Physics Studies

The peculiar size-dependent reactivity of Ag n + ( n = 2–22) with O 2 can be attributed to varying HOMO–LUMO gaps of clusters, which correlate with the subtle interplay between their electronic properties and geometric structures.