De novo synthesis of inherently chiral heteracalix[4]aromatics from enantioselective macrocyclization enabled by chiral phosphoric acid-catalyzed intramolecular S N Ar reaction

作者：Xingchi Li, Ying Cheng, Xudong Wang, Shuo Tong, Mei‐Xiang Wang · 发表于：Chemical Science · 年份：2024 · DOI：10.1039/d3sc06436k · 被引用次数：48 · 研究领域：Supramolecular Chemistry and Complexes、Molecular Sensors and Ion Detection、Porphyrin and Phthalocyanine Chemistry

,O-calix[2]arene[2]triazines from enantioselective macrocyclization enabled by chiral phosphoric acid-catalyzed intramolecular nucleophilic aromatic substitution reaction. In contrast to documented examples, the inherent chirality of the acquired compounds arises from one heteroatom difference in the linking positions of heteracalix[4](het)arenes.