Eu 3+ ‐Directed Supramolecular Metallogels with Reversible Quadruple‐Stimuli Response Behaviors

作者：Yan Chen, Huimin Li, Yakun Zhang, Zhiqiang Li, Daqing Yang · 发表于：Small · 年份：2024 · DOI：10.1002/smll.202309542 · 被引用次数：15 · 研究领域：Supramolecular Chemistry and Complexes、Supramolecular Self-Assembly in Materials、Metal-Organic Frameworks: Synthesis and Applications

Abstract Smart luminescent materials that have the ability to reversibly adapt to external environmental stimuli and possess a wide range of responses are continually emerging, which place higher demands on the means of regulation and response sites. Here, europium ions (Eu 3+ )‐directed supramolecular metallogels are constructed by orthogonal self‐assembly of Eu 3+ based coordination interactions and hydrogen bonding. A new organic ligand ( L ) is synthesized, consisting of crown ethers and two flexible amide bonds‐linked 1,10‐phenanthroline moieties to coordinate with Eu 3+ . Synergistic intermolecular hydrogen bonding in L and Eu 3+ ‐ L coordination bonding enable Eu 3+ and L to self‐assemble into shape‐persistent 3D coordination metallogels in MeOH solution. The key to success is the utilization of crown ethers, playing dual roles of acting both as building blocks to build L with C 2 ‐symmetrical structure, and as the ideal monomer for increasing the energy transfer from L to Eu 3+ ’s excited state, thus maintaining the excellent luminescence of metallogels. Interestingly, such assemblies show K + , pH, F − , and mechano‐induced reversible gel‐sol transitions and tunable luminescence properties. Above findings are useful in the studies of molecular switches, dynamic assemblies, and smart luminescent materials.